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Printable graphene inks enable ultrafast lasers in the terahertz range.

Graphene Flagship researchers from CNR-Istituto Nanoscienze in Italy and the University of Cambridge in the U.K. have shown that it is possible to create a terahertz saturable absorber using graphene produced by liquid phase exfoliation and deposited by transfer coating and ink jet printing. The paper, published in Nature Communications, reports a terahertz saturable absorber with an order of magnitude higher absorption modulation than other devices produced to date.

A terahertz saturable absorber decreases its absorption of light in the terahertz range (far infrared) with increasing light intensity and has great potential for the development of terahertz lasers, with applications in spectroscopy and imaging. These high-modulation, mode-locked lasers open up many prospects in applications where short time scale excitation of specific transitions are important, such as time-resolved spectroscopy of gasses and molecules, quantum information or ultra-high speed communication.

“We started working on saturable terahertz absorbers to solve the problem of producing a miniaturized mode-locked terahertz laser with thin and flexible integrated components that also had good modulation,” says Graphene Flagship researcher Miriam Vitiello from CNR-Istituto Nanoscienze.

Graphene is a promising saturable absorber as it has intrinsic broadband operations and ultrafast recovery time along with an ease of fabrication and integration, as first demonstrated in ultra-fast infra-red lasers by Flagship partner University of Cambridge. In the terahertz range, the present paper exploits graphene produced by liquid phase exfoliation, a method ideally suited to mass production, to prepare inks, easily deposited by transfer coating or ink jet printing.

“It was important to us to use a type of graphene that could be integrated into the laser system with flexibility and control,” says Vitiello. “Ink jet printing along with transfer coating achieved that.”

Using mode-locked lasers to produce ultrafast pulses in the terahertz range can have interesting and exciting uses. “These devices could have applications in medical diagnostics when time of flight topography is of importance — you could see a tumor inside a tissue,” says Vitiello.

Frank Koppens of the Institute of Photonic Sciences in Spain is the leader of the Graphene Flagship’s Photonics and Optoelectronics Work Package, which focuses on developing graphene-based technologies for imaging and sensing, data transfer and other photonics applications. “This is a new discovery with immediate impact on applications. Clearly, this is a case where graphene beats existing materials in terms of efficiency, scalability, compactness, and speed,” he says.

Andrea C. Ferrari, Science and Technology Officer of the Graphene Flagship and Chair of its Management Panel, adds, “It is an important milestone to have demonstrated that easily produced and printable graphene inks can also serve to enable ultrafast lasers in the terahertz range. Since the Flagship’s inception, a variety of lasers have been made covering the visible to IR spectral range, but now the important THz range, with applications in security and medical diagnostic, is finally made accessible by graphene, starting yet another possible application field.”

Source: Graphene Flagship

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